Hydrous Sodium Silicates from Lake Magadi, Kenya: Precursors of Bedded Chert

Abstract

Two new hydrous sodium silicates, NaSi₇O₁₃(OH)₃·3H₂O (magadiite) and NaSi₁₁O_20.5(OH)₄·3H₂O (kenyaite), were found in lake beds at Lake Magadi, Kenya. Both are well-crystallized layered silicates with large basal spacings. Concretions within the magadiite bed consist of kenyaite or quartz (chert) in the center, surrounded by kenyaite. In dilute acids magadiite and kenyaite are converted to 6SiO₂·H₂O (SH), the first known crystalline hydrate of silica. The magadiite bed probably represents a chemical precipitate from alkaline brines. Percolating waters convert magadiite to kenyaite and eventually to chert. Thus a mechanism has been outlined for the formation of bedded chert deposits through inorganic precipitation. Alternations between silica-rich and iron-rich bands of iron formations may be due to concentration cycles in alkaline lakes.