Synthesis of an Amino‐Functionalized Model of the Fe‐Only Hydrogenase Active Site
- 16 January 2003
- journal article
- Published by Wiley in Chemistry – A European Journal
- Vol. 9 (2), 557-560
- https://doi.org/10.1002/chem.200390058
Abstract
A dinuclear 2Fe2S mimic 6 of the active site of the Fe‐only hydrogenases has been synthesized. Complex 6 contains a free amino group which enables linkage to a protein backbone or to a redox active species for the study of electron transfer processes in proteins or in supramolecular systems. The structures of the complex 6 and its Boc‐protected precursor 5 could be verified by X‐ray crystallography.Keywords
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