Growth and properties of single crystals of group I-III-VI2 ternary semiconductors

Abstract
Single crystals of five members of the I-III-VI2 ternary semiconductors have been grown by iodine vapour transport and variations of growth are reported. The measured energy gaps are 244 eV (CuGaS2), 206 eV (CuAlTe2), 251-261 eV (AgGaS2), 313 eV (AgAlS2) and 255 eV (AgAlSe2). The refractive index for CuGaS2 varies from 2825 at 525 nm to 2660 at 661 nm with refractive indices of 2720 and 2724 for two polarizations at 5892 nm.

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