Spectroscopic analysis, coordination geometry, and x-ray structures of nickel(II) compounds with sterically demanding tris(pyrazolyl)borate ligands and azide or (thio)cyanate anions. Crystal and molecular structures of bis[(.mu.-thiocyanato-N,S)(hydrotris(3-isopropyl-4-bromopyrazol-1-yl)borato)nickel(II)]-3-heptane and (thiocyanato-N)(hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borato)nickel(II)

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