Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates
- 1 September 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (17), 3225-3235
- https://doi.org/10.1080/00397919608004631
Abstract
Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-allyl ruthenium complex.Keywords
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