InxGa1−xN single‐crystal films were grown at 600–700 °C by atomic layer epitaxy (ALE). InGaN films with compositions of up to 27% indium were achieved. The full width at half‐maximum (FWHM) of the (0002) InxGa1−xN peak by double crystal x‐ray diffraction (DCXRD) was as small as 6 min, the lowest value reported for this ternary alloy. Strong photoluminescence band edge emission between 360 and 446 nm was observed at room temperature. These low temperature ALE grown films were achieved without the need to use excessive flows of the In organometallic source and thus demonstrate the potential for growth of this ternary alloy over the entire composition range.