Semiclassical Transition Probabilities (S Matrix) of Vibrational—Translational Energy Transfer
- 15 December 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (12), 5663-5667
- https://doi.org/10.1063/1.1675736
Abstract
Uniformized coordinates and an integral expression for the semiclassical S matrix, derived elsewhere, are described and applied to vibrational transition probabilities. The expression obeys microscopic reversibility. The numerical results are compared with the exact quantum mechanical results of Secrest and Johnson.Keywords
This publication has 14 references indexed in Scilit:
- Theory of Semiclassical Transition Probabilities for Inelastic and Reactive Collisions. II Asymptotic Evaluation of the S MatrixThe Journal of Chemical Physics, 1971
- A theory of vibrational excitation in the near classical limitChemical Physics Letters, 1971
- Extension of the WKB method to wave functions and transition probability amplitudès (S-matrix) for inelastic or reactive collisionsChemical Physics Letters, 1970
- On the classical and semiclassical limits in collision theoryChemical Physics Letters, 1970
- The classical S-matrix: a more detailed study of classically forbidden transitions in inelastic collissionsChemical Physics Letters, 1970
- Semiclassical Theory of Atom–Diatom Collisions: Path Integrals and the Classical S MatrixThe Journal of Chemical Physics, 1970
- Classical collisions and correspondence principleJournal of Physics B: Atomic and Molecular Physics, 1970
- Vibrational–Translational Energy Transfer in the Near-Adiabatic ApproximationThe Journal of Chemical Physics, 1970
- Time-Dependent Semiclassical Scattering Theory. I. Potential ScatteringPhysical Review B, 1969
- Quasi-Classical Transformation TheoryPhysical Review B, 1962