A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO–containing poly(alkoxyamine ester)s
- 28 October 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 23,p. 2838-2839
- https://doi.org/10.1039/b209193c
Abstract
A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.Keywords
This publication has 18 references indexed in Scilit:
- Dynamic Covalent ChemistryAngewandte Chemie International Edition, 2002
- Production of crosslinked, hollow nanoparticles by surface‐initiated living free‐radical polymerizationJournal of Polymer Science Part A: Polymer Chemistry, 2002
- Supramolecular PolymersChemical Reviews, 2001
- New Polymer Synthesis by Nitroxide Mediated Living Radical PolymerizationsChemical Reviews, 2001
- End-group fidelity in nitroxide-mediated living free-radical polymerizationsJournal of Polymer Science Part A: Polymer Chemistry, 2000
- Supramolecular PolymersPublished by Taylor & Francis ,2000
- Radical Crossover in Nitroxide Mediated “Living” Free Radical PolymerizationsJournal of the American Chemical Society, 1996
- Molecular Weight Control by a "Living" Free-Radical Polymerization ProcessJournal of the American Chemical Society, 1994
- Supramolecular chemistry — Molecular information and the design of supramolecular materialsMakromolekulare Chemie. Macromolecular Symposia, 1993
- Thermally reversible, covalently crosslinked polyphosphazenesJournal of Polymer Science Part A: Polymer Chemistry, 1988