Optical transitions ofEr3+ions in fluorozirconate glass

Abstract

Optical-absorption, -emission, and -excitation spectra are presented for ${\mathrm{Er}}^{3+}$ ions in fluorozirconate glass. Measured oscillator strengths of the transitions between $J$ manifolds at 300 and 15 K are compared with calculated electric and magnetic dipole oscillator strengths. Radiative rates for five luminescing states were calculated. The nonradiative rates from these excited states were determined by calculating the difference between the measured rates and the calculated radiative rates. The low-temperature nonradiative rates are in agreement with the phenomenological energy-gap law followed by rare-earth ions in a number of crystals and glasses. The temperature dependence of the lifetimes was analyzed using the Huang-Rhys theory of multiphonon emission. Values for the ${}_{}{}^4{}_{}{}^{}I_{\frac{11}{2}}^{}{}_{}{}^{}$ radiative and nonradiative rates obtained by the above methods are compared with those obtained applying the method Flaherty and DiBartolo used to study Mn${\mathrm{F}}_2$: ${\mathrm{Er}}^{3+}$. The multiphonon emission rates in fluorozirconate glass are much lower than the rates for the same levels of ${\mathrm{Er}}^{3+}$ in oxide glasses. Measurements of the bandwidths of the ground and excited states of ${\mathrm{Er}}^{3+}$ and the nearly exponential decay of the emissions indicate a relatively narrow distribution of site symmetries compared to oxide glasses.