Enhanced photoluminescence of Eu3+ induced by energy transfer from In2O3 nano-crystals embedded in glassy matrix

Abstract

Eu³⁺-doped transparent glass ceramics containing In₂O₃ nano-crystals were prepared by melt quenching and subsequent heating. X-ray diffraction analysis, transmission electron microscope observation, and photoluminescence excitation spectra demonstrated that In₂O₃ nano-particles sized 3–6 nm homogenously distributed among the glass matrix. Under excitation of these nano-particles, Eu³⁺ luminescence was found greatly enhanced due to the energy transfer from the oxygen-vacancy-related defects of In₂O₃ to Eu³⁺ ions. The Eu³⁺ content dependent energy transfer efficiency was evaluated, and the value reached 67% for 1 mol% Eu³⁺ doped glass ceramics. Low temperature emission spectra demonstrated that the Eu³⁺ ions of the glass ceramic locate mainly in the glass matrix.