Syntheses of diethyleneoxy bridged cryptophanes and their complexing abilities with alkali metal and alkylammonium cations
- 1 July 1996
- journal article
- research article
- Published by Taylor & Francis in Supramolecular Chemistry
- Vol. 7 (3), 187-193
- https://doi.org/10.1080/10610279608027515
Abstract
The anti- and syn-diethyleneoxy bridged cryptophanes (3a and 3b) were prepared by the direct trimerization of 1,5-bis[(4-hydroxymethyl)-2-methoxyphenoxy]-3-oxapentane, which was obtained by the reaction of diethyleneglycol ditosylate with vanillyl alcohol and/or by stepwise methods from vanillyl alcohol. The syn isomer (3b) showed highly selective complexing abilities for cesium, and the tetraethylammonium and triethylmethylammonium cations as compared with those of the anti isomer (3a).Keywords
This publication has 16 references indexed in Scilit:
- Remarkable effect of the receptor size in the binding of acetylcholine and related ammonium ions to water-soluble cryptophanesJournal of the American Chemical Society, 1993
- Structure and Properties of the Cryptophane‐E/CHCl3 Complex, a Stable van der Waals MoleculeAngewandte Chemie International Edition in English, 1989
- Two-step synthesis of D 3 and C 3h cryptophanesJournal of the Chemical Society, Chemical Communications, 1988
- Cyclotriveratrylenes and cryptophanesTetrahedron, 1987
- A new cryptophane forming unusually stable inclusion complexes with neutral guests in a lipophilic solventJournal of the American Chemical Society, 1986
- Analytical optical resolution of bromochlorofluoromethane by enantioselective inclusion into a tailor-made cryptophane and determination of its maximum rotationJournal of the American Chemical Society, 1985
- A new bis-cyclotribenzyl cavitand capable of selective inclusion of neutral molecules in solution. Crystal structure of its CH2Cl2 cavitateJournal of the Chemical Society, Chemical Communications, 1985
- Synthesis of a (D 3)-bis(cyclotriveratrylenyl) macrocage by stereospecific replication of a (C 3)-subunitJournal of the Chemical Society, Chemical Communications, 1981
- Ligandstruktur und Komplexierung, LII. Notiz über Kronenether mit Triveratrylen‐GerüstEuropean Journal of Organic Chemistry, 1979
- Enthalpy and Entropy of Formation of Alkali and Alkaline‐Earth Macrobicyclic Cryptate Complexes [1]Helvetica Chimica Acta, 1976