On the spectroscopic consequences of different tunnelling mechanisms in non-rigid phosphorus pentafluoride (II)
- 1 June 1976
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 31 (6), 1887-1895
- https://doi.org/10.1080/00268977600101481
Abstract
In this paper the spacings between the non-rigid molecule levels for each conceivable tunnelling pathway of phosphorus pentafluoride are parametrized. The theoretical spectra corresponding to each isomerization mode of this molecule are obtained and are shown to lead to new ways of discriminating the various isomerization modes.Keywords
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