Uranyl Ion Coordination
- 12 July 1963
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 141 (3576), 154-158
- https://doi.org/10.1126/science.141.3576.154
Abstract
A review of the known crystal structures containing the uranyl ion shows that plane-pentagon coordination is equally as prevalent as planesquare or plane-hexagon. It is suggested that puckered-hexagon configurations of OH- or H2O about the uranyl group will tend to revert to plane-pentagon coordination. The concept oft of pentagonal coordination is invoked for possible explanations of the complex crystallography of the natural tiranyl hydroxides and the unusual behavior of polynuclear ions in hydrolyzed uranyl solutions.Keywords
This publication has 17 references indexed in Scilit:
- Aqueous systems at high temperature—VIII: The solubility of UO3 hydrates in HNO3H2O solutions, 25–350°C, 10−4−6 molal nitrateJournal of Inorganic and Nuclear Chemistry, 1963
- Comments to B. S. Jensen's Paper "The Formation of Polynuclear Complexes".Acta Chemica Scandinavica, 1962
- The crystal structure of cesium biuranyl trisulphate, Cs2(UO2)2(SO4)3Journal of Inorganic and Nuclear Chemistry, 1960
- Crystal chemical studies of the 5f-series of elements. XXV. The crystal structure of sodium uranyl acetateActa Crystallographica, 1959
- Studies on the Hydrolysis of Metal Ions. 24. Hydrolysis of the Uranyl Ion, UO2+2, in Perchlorate Self-Medium.Acta Chemica Scandinavica, 1959
- The structure of U3O8determined by neutron diffractionActa Crystallographica, 1958
- X-Ray Investigations on Uranyl Hydroxides. I. The Crystal Structure of beta-UO2(OH)2.Acta Chemica Scandinavica, 1956
- Crystal Structure of Rutherfordine, UO 2 CO 3Science, 1955
- Crystal chemical studies of the 5f-series of elements. XXI. The crystal structure of magnesium orthouranateActa Crystallographica, 1954
- On the composition and the crystallography of autunite and the meta‐autunitesRecueil des Travaux Chimiques des Pays-Bas, 1938