Reaction of N-propyl-1,4-dihydronicotinamide with ferricyanide ion
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 181-182
- https://doi.org/10.1039/c39770000181
Abstract
The reaction of N-propyl-1,4-dihydronicotinamide (PNAH) with ferricyanide ion follows a secondorder rate law with rate =k[Fe(CN)6 3–][PNAH], ΔH‡ 2 kcal mol–1, ΔS‡–43 cal mol–1 K–1 and an observed kinetic deuterium isotope effect, kH/kD, of 1·68.This publication has 2 references indexed in Scilit:
- Reactions of perhaloacetones with dihydropyridines and other electron donorsThe Journal of Organic Chemistry, 1976
- Model dehydrogenase reactions. Zinc ion catalyzed reduction of chelating aldehydes by N-propyl-1,4-dihydronicotinamides and borohydrideJournal of the American Chemical Society, 1976