ENDOR studies on a rotating methyl group
- 1 January 1967
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 12 (2), 159-164
- https://doi.org/10.1080/00268976700100211
Abstract
The radical CH3CHCOOH has been identified by ENDOR measurements as a minor product of the irradiation of succinic acid with x-rays at room temperature. The rotating methyl group gives fairly sharp ENDOR transitions which show second-order splitting. The relative intensities of the transitions suggest a strong relaxation mechanism associated with a time dependent scalar coupling.Keywords
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