N.m.r. and conformational studies on some 1,3-linked disaccharides
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 2,p. 209-217
- https://doi.org/10.1039/p19880000209
Abstract
13 C and 1H N.m.r. data have been obtained from 10 methyl 6-deoxyhexosylhexosides in which the 6-deoxysugar is the L- or D-enantiomer of fucose or rhamnose. A large variation in the magnitude of displacement shifts of signals for α- and β-carbons is observed. For all compounds Hard Sphere Exo Anomeric effect (HSEA) calculations have been performed to estimate favoured conformations. From the derived minimum energy conformations, a number of 1H n.m.r. chemical shifts can be rationalised.This publication has 8 references indexed in Scilit:
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