First cation radical salt of a tetrathiafulvalene–based phosphine metal complex
- 5 May 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 11,p. 1300-1301
- https://doi.org/10.1039/b403168g
Abstract
Electrocrystallization of (o-P2)Mo(CO)4, where o-P2 is the tetrathiafulvalene-based chelating diphosphine o-Me2TTF-(PPh2)2, in the presence of the Linquist anion Mo6O19 2− affords a 2:1 salt, formulated as [(o-P2)Mo(CO)4]2[Mo6O19], with a Heisenberg spin chain magnetic behaviour.Keywords
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