Zeeman–quadrupole cross relaxation between two nuclear spin species
- 15 April 1979
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 70 (8), 3572-3576
- https://doi.org/10.1063/1.437959
Abstract
We derive an expression for the rate τ−1IS of the cross relaxation between the Zeeman splitting of one nuclear spin species (I spins, I=1/2) and the quadrupole splitting of another spin species (S spins, S≳1/2) via the I–S dipolar interaction. We calculate τIS for the case of CFCL2–CFCL2 (I spins are 19F, and S spins are 35Cl and 37Cl) and compare the results with experimental data.Keywords
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