Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
Open Access
- 3 June 2015
- journal article
- Published by Beilstein Institut in Beilstein Journal of Organic Chemistry
- Vol. 11 (1), 951-956
- https://doi.org/10.3762/bjoc.11.106
Abstract
A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy.Keywords
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