Zinc Oxide-Eugenol Cements: IV. Microstructure and Hydrolysis

Abstract
The microstructure of zinc oxide-eugenol cement and the water-leached product was examined by electron microscopy and scanning electron microscopy. Crystalline zinc eugenolate, which forms a reaction product, encases and binds unconsumed zinc oxide grains. Water leaching removes zinc eugenolate and leaves a voided structure bound by zinc hydroxide, which readily disintegrates.

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