ARYLPYRIDINES: PART II. REACTION OF PHENYLLITHIUM WITH 3-METHOXY- AND 3-AMINO-PYRIDINE
- 1 September 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (9), 1445-1448
- https://doi.org/10.1139/v60-203
Abstract
Phenyllithium has been shown to react with 3-methoxy- and 3-amino-pyridine to give exclusively 3-methoxy-2-phenylpyridine and 3-amino-2-phenylpyridine respectively. The orientation of the products has been established unambiguously. None of the 2,5-isomer was detected in either case. An explanation for this unique orientation is suggested.Keywords
This publication has 3 references indexed in Scilit:
- ARYLPYRIDINES: PART I. ORIENTATION IN THE REACTION OF PHENYLLITHIUM WITH SOME 3-SUBSTITUTED PYRIDINESCanadian Journal of Chemistry, 1960
- DIFFERENTIATION BETWEEN SOME 2,3- AND 2,5-DISUBSTITUTED PYRIDINE DERIVATIVES BY INFRARED SPECTROSCOPYCanadian Journal of Chemistry, 1960
- Studies in Stereochemistry. XXX. Models for Steric Control of Asymmetric Induction1Journal of the American Chemical Society, 1959