Investigations of Rotation of Axial Ligands in Six-Coordinate Low-Spin Iron(III) Tetraphenylporphyrinates: Measurement of Rate Constants from Saturation Transfer Experiments and Comparison to Molecular Mechanics Calculations
- 1 April 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Physical Chemistry A
- Vol. 101 (15), 2787-2795
- https://doi.org/10.1021/jp963235z
Abstract
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This publication has 25 references indexed in Scilit:
- 2D NMR Investigations of the Rotation of Axial Ligands in Six-Coordinate Low-Spin Iron(III) and Cobalt(III) Tetraphenylporphyrinates Having 2,6-Disubstituted Phenyl Rings: Quantitation of Rate Constants from 1H EXSY Cross-Peak IntensitiesThe Journal of Physical Chemistry A, 1997
- Analysis of the Temperature Dependence of the 1H Contact Shifts in Low-Spin Fe(III) Model Hemes and Heme Proteins: Explanation of "Curie" and "Anti-Curie" Behavior within the Same MoleculeThe Journal of Physical Chemistry, 1995
- NMR Studies of Hindered Ligand Rotation, Magnetic Anisotropy, Curie Behavior, Proton Spin Relaxation, and Ligand Exchange in Some Novel Oxomolybdenum(V)/Iron(III) Porphyrinate ComplexesJournal of the American Chemical Society, 1995
- Rotation and orientation of axially coordinated imidazoles in low-spin ferric porphyrin complexesInorganica Chimica Acta, 1994
- Axial Ligand Orientation in Iron(III) Porphyrinates: Effect of Axial .pi.-Acceptors. Characterization of the Low-Spin Complex [Fe(TPP)(4-CNPy)2]ClO4Journal of the American Chemical Society, 1994
- Models of the cytochromes b. Low-spin bis-ligated (porphinato)iron(III) complexes with unusual molecular structures and NMR, EPR, and Moessbauer spectraJournal of the American Chemical Society, 1992
- Models of the cytochromes b. 8. Two-dimensional nuclear Overhauser and exchange spectroscopy studies of paramagnetic "cavity" type (tetraphenylporphinato)iron(III) complexes of planar ligandsJournal of the American Chemical Society, 1991
- Models of the cytochromes b. Control of axial ligand orientation with a hindered porphyrin systemJournal of the American Chemical Society, 1991
- Hindered rotation of axially coordinated 2-methylimidazoles in tetramesitylporphyrinato-iron(III) complexesTetrahedron, 1988
- Models of the cytochromes b. Effect of axial ligand plane orientation on the EPR and Moessbauer spectra of low-spin ferrihemesJournal of the American Chemical Society, 1986