Utilizing fluorescein methacrylate as fluorescent functional monomer on synthesizing fluorescent molecularly imprinted polymer in sensing caffeine
- 13 July 2018
- proceedings article
- Published by AIP Publishing in AIP Conference Proceedings
- Vol. 1985 (1), 050005
- https://doi.org/10.1063/1.5047199
Abstract
In this study describes the fluorescein methacrylate (FMA) used as fluorescence functional monomer in the synthesis of caffeine-imprinted fluorescence polymers (Caf-FMIP) for the selective recognition of caffeine. The Caf-FMIP was synthesized using bulk polymerization with non-covalent imprinting approach and the formation of ˗NH groups had interaction with caffeine and FMA moieties was confirmed by using Fourier transform infrared spectroscopy (FT-IR). The absorption isotherm analysis of Caf-FMIP favors Freundlich model suggested the forming heterogeneous surface was occurred due to non-covalent imprinting approach. Fluorescence emissions of synthesized Caf-FMIP were ‘switched on’ in the presence of target molecule based on photo-induce electron transfer (PET) mechanism. In addition, Caf-FMIP fluorescence was enhanced more strongly by caffeine compared to non-imprinted polymer, which indicated that caffeine could recognized by the Caf-FMIP selectively.Keywords
This publication has 19 references indexed in Scilit:
- Monitoring bisphenol A and its biodegradation in water using a fluorescent molecularly imprinted chemosensorChemosphere, 2015
- Molecular imprinting-based fluorescent optosensor using a polymerizable 1,8-naphthalimide dye as a florescence functional monomerSensors and Actuators B: Chemical, 2014
- Optimisation of the synthesis of vancomycin-selective molecularly imprinted polymer nanoparticles using automatic photoreactorNanoscale Research Letters, 2014
- Highly Selective Fluorescent Sensing of Proteins Based on a Fluorescent Molecularly Imprinted NanosensorSensors, 2013
- Fluorescent monomers as building blocks for dye labeled polymers: synthesis and application in energy conversion, biolabeling and sensorsChemical Society Reviews, 2013
- Synthesis and characterization of novel polymers bearing fluorescein units: thermal and optical propertiesDesigned Monomers and Polymers, 2012
- Fluorescent PET (Photoinduced Electron Transfer) sensors as potent analytical toolsThe Analyst, 2009
- Characterization of binding sites in molecularly imprinted polymersSensors and Actuators B: Chemical, 2007
- Imprinting polymerisation for recognition and separation of metal ionsPublished by Elsevier ,2001
- The synthesis of some 1,8-naphthalic anhydride derivatives as dyes for polymeric materialsDyes and Pigments, 1993