Vibrational Assignments of Organosilanetriols. II. Crystalline Phenylsilanetriol and Phenylsilanetriol-D3
- 1 September 1978
- journal article
- research article
- Published by SAGE Publications in Applied Spectroscopy
- Vol. 32 (5), 469-479
- https://doi.org/10.1366/000370278774330874
Abstract
Fourier transform infrared spectra (3800 to 450 cm−1) and laser Raman spectra (4000 to 0 cm−1) of crystalline phenylsilanetriol and phenylsilanetriol-d3, and liquid state phenylsilanetriol and phenylsilanetriol-d3 are first reported. Complete band assignments are attempted. All vibrational modes of the SiOH group except for the SiC torsional mode, including the SiOH in-plane and out-of-plane bending modes, are observed. In addition to the phenylsilanetriols, infrared and laser Raman spectra of crystalline diphenylsilanediol and triphenylsilanol are also studied to aid the band assignments.Keywords
This publication has 12 references indexed in Scilit:
- Vibrational Assignments of Organosilanetriols. I. Vinylsilanetriol and Vinylsilanetriol-D3 in Aqueous SolutionsApplied Spectroscopy, 1978
- Vibrational spectra and structure of some silicon containing compounds—IV: Normal vibrations and free rotation in phenylsilaneSpectrochimica Acta Part A: Molecular Spectroscopy, 1972
- A valence force field for alkyl benzenes Toluene, p-xylene, m-xylene mesitylene, and some of their deuterated analoguesSpectrochimica Acta Part A: Molecular Spectroscopy, 1971
- Low-frequency Raman spectrum of benzoic single crystalsSpectrochimica Acta Part A: Molecular Spectroscopy, 1971
- Vibrational Spectra and Structure of Organogermanes. IV. Normal Vibrations and Free Rotation in PhenylgermaneThe Journal of Chemical Physics, 1968
- Low frequency vibrational spectra of group IV-A phenyl compoundsSpectrochimica Acta Part A: Molecular Spectroscopy, 1968
- Infrared and Raman Spectra of C6H5SiCl3, C6H5GeCl3, and C6H5SnCl3The Journal of Chemical Physics, 1966
- Infrared and Raman Spectra of α,α,α-Trichlorotoluene, C6H5CCl3The Journal of Chemical Physics, 1965
- The vibrational spectra and assignments of nitrobenzene, phenyl isocyanate, phenyl isothiocyanate, thionylaniline and anisoleSpectrochimica Acta, 1961
- PhenylsilanetriolJournal of the American Chemical Society, 1955