PERFLUOROALKYL ARSENICALS: PART I. THE PREPARATION OF ALKYL PERFLUOROALKYL ARSENICALS
- 1 March 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (3), 439-444
- https://doi.org/10.1139/v60-059
Abstract
The reaction of tetramethyldiarsine with trifluoroiodomethane gives dimethyltrifluoromethylarsine. Trifluoroiodomethane and iodomethane similarly react with the compounds (CF3)2M—M(CF3)2 to give the compounds (CF3)3M and (CF3)2MCH3 respectively (M = As or P). Trifluoroiodomethane reacts with iododimethylarsine and diiodomethylarsine in the presence of mercury to give dimethyltrifluoromethylarsine and methylbistrifluoromethylarsine respectively. Heptafluoropropyldimethylarsine can be isolated from a similar reaction using heptafluoroiodopropane.Keywords
This publication has 1 reference indexed in Scilit:
- The Cyclopolyphosphines (CF3P)4 and (CF3P)5, and Related Chemistry1Journal of the American Chemical Society, 1958