Rotational transitions in molecule–solid scattering
- 1 April 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (7), 2730-2735
- https://doi.org/10.1063/1.430805
Abstract
A quantum mechanical calculation of the collision of H2 with the (001) face of LiF has been carried out and compared with recent experimental data in which rotational transitions were resolved. A simple model potential accounts quantitatively for many of the observed effects. Refined potential parameters are extracted and the effects of some of these parameters on rotational transitions are discussed.Keywords
This publication has 17 references indexed in Scilit:
- Effect of changes in the potential on atom-solid elastic scatteringThe Journal of Chemical Physics, 1974
- Semiclassical theory of atom-solid surface collisions: Elastic scatteringChemical Physics, 1974
- Interaction potential for He/H2 including the region of the van der waals minimumChemical Physics Letters, 1973
- The diffraction of H2, D2 from solid LiFChemical Physics Letters, 1973
- Computed potential hypersurface (including electron correlation) of the system Li+/H2Chemical Physics, 1973
- Surface Debye temperature by atomic beam scatteringSurface Science, 1972
- Intensity data for the reflection and diffraction of 3He, 4He, H2 AND D2 From the (001) Surface of LiFSurface Science, 1970
- Scattering of atoms by solid surfaces. ISurface Science, 1970
- Helium-Atom–Hydrogen-Molecule Potential Surface Employing the LCAO–MO–SCF and CI MethodsThe Journal of Chemical Physics, 1970
- Theoretical Studies of Proton-Transfer Reactions. I. Reactions of Hydride Ion with Hydrogen Molecules.Journal of the American Chemical Society, 1968