Complete Study of the Pyrolysis and Gasification of Scrap Tires in a Pilot Plant Reactor
- 23 April 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Environmental Science & Technology
- Vol. 38 (11), 3189-3194
- https://doi.org/10.1021/es034608u
Abstract
The pyrolysis and gasification of tires was studied in a pilot plant reactor provided with a system for condensation of semivolatile matter. The study comprises experiments at 450, 750, and 1000 °C both in nitrogen and 10% oxygen atmospheres. Analysis of all the products obtained (gases, liquids, char, and soot) are presented. In the gas phase only methane and benzene yields increase with temperature until 1000 °C. In the liquids the main components are styrene, limonene, and isoprene. The solid fraction (including soot) increases with temperature. Zinc content of the char decreases with increasing temperature.Keywords
This publication has 11 references indexed in Scilit:
- Evolution of Products in the Combustion of Scrap Tires in a Horizontal, Laboratory Scale ReactorEnvironmental Science & Technology, 2000
- Tire Pyrolysis: Evolution of Volatile and Semivolatile CompoundsEnergy & Fuels, 2000
- Kinetic model for the combustion of tyre wastesFuel, 1998
- Gas from the Pyrolysis of Scrap Tires in a Fluidized Bed ReactorEnergy & Fuels, 1996
- Evolved gas analysis of pyrolysis products from some rubbers by mass spectrometryEuropean Polymer Journal, 1991
- Natural rubber pyrolysis: Study of temperature-and thickness-dependence indicates dimer formation mechanismJournal of Analytical and Applied Pyrolysis, 1991
- Chemorheology of crosslinked polyisoprene/poly(butadiene co-styrene) blendsJournal of Applied Polymer Science, 1987
- The degradation of guayule rubber and the effect of resin components on degradation at high temperatureJournal of Applied Polymer Science, 1987
- Polymer reactions—X thermal pyrolysis of poly(isoprene)European Polymer Journal, 1979
- The effect of heating rate on the thermal degradation of polybutadieneJournal of Applied Polymer Science, 1978