STEREOSELECTIVE SYNTHESIS OF OPTICALLY ACTIVE MANICONES: ALARM PHEROMONE OF ANT
- 5 March 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 5 (3), 279-282
- https://doi.org/10.1246/cl.1976.279
Abstract
(+)- and (−)-Manicone, (+)-(6S)- and (−)-(6R)-(4E)-4,6-dimethyl-4-octen-3-one, were synthesized in good yields by the TiCl4-promoted reaction of 3-trimethylsiloxy-2-pentene with (+)-(2S)- or (−)-(2R)-2-methylbutanal.Keywords
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