A new electronic emission system of TiN has been observed in the violet region of the spectrum. It is the pure precession companion state B2Σ, of the previously known red A2Π → X2Σ system. Rotational analysis yielded the constants B0′ = 0.5745 cm−1, D0′ = 6.4 × 10−7 cm−1, and T0 = 23 487 cm−1.