Retarded Long-Range Interaction in He Rydberg States

Abstract
We calculate the energy shifts, in Rydberg states of helium, due to retardation corrections to the two-photon exchange potential. The correction to the level spacings is at the accuracy of existing measurements in the n=10 states of neutral He. It may soon be possible for the first time to detect the effect of these corrections in atomic systems. Estimates of the energy shifts for high-Z He-like ions yield effects of several percent of the total spacing.