Wigner phase space method: Analysis for semiclassical applications
- 15 August 1976
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 65 (4), 1289-1298
- https://doi.org/10.1063/1.433238
Abstract
We investigate the suitability of the Wigner method as a tool for semiclassical dynamics. In spite of appearances, the dynamical time evolution of Wigner phase space densities is found not to reduce to classical dynamics in most circumstances, even as h→0. In certain applications involving highly ’coherent’ density matrices, this precludes direct h‐expansion treatment of quantum corrections. However, by selective resummation of terms in the Wigner–Moyal series for the quantum phase space propagation it is possible to arrive at a revised or renormalized classicallike dynamics which solves the difficulties of the direct approach. In this paper, we review the Wigner method, qualitatively introduce the difficulties encountered in certain semiclassical applications, and derive quantitative means of surmounting these difficulties. Possible practical applications are discussed.Keywords
This publication has 19 references indexed in Scilit:
- Quantum mechanical transition state theory and a new semiclassical model for reaction rate constantsThe Journal of Chemical Physics, 1974
- Quantum Corrections to the Momentum Relaxation Time of a Brownian ParticleThe Journal of Chemical Physics, 1969
- Quantum Corrections to Time Correlation FunctionsThe Journal of Chemical Physics, 1968
- On the statistical mechanical theory of Brownian motion. IIPhysica, 1967
- Quasiclassical Theory of Neutron ScatteringPhysical Review B, 1965
- The wigner distribution function for systems of bosons or fermionsPhysica, 1959
- Temperature Dependence of Distribution Functions in Quantum Statistical MechanicsPhysical Review B, 1957
- The Statistical Mechanical Theory of Transport Processes. V. Quantum HydrodynamicsThe Journal of Chemical Physics, 1951
- Quantum mechanics as a statistical theoryMathematical Proceedings of the Cambridge Philosophical Society, 1949
- On the Quantum Correction For Thermodynamic EquilibriumPhysical Review B, 1932