Effective Diffusion Constant in a Polyelectrolyte Solution
- 15 February 1963
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 38 (4), 959-968
- https://doi.org/10.1063/1.1733791
Abstract
A general theory of the effective diffusion constant of ions in a periodic electric field is presented. The predictions of the theory are compared with the results of experiments on the diffusion of labeled sodium in a sodium hydroxide—polyacrylic acid solution.Keywords
This publication has 3 references indexed in Scilit:
- On the Self-Diffusion of Ions in a Polyelectrolyte SolutionThe Journal of Chemical Physics, 1962
- Numerical Solution to the Poisson-Boltzmann Equation for Spherical Polyelectrolyte MoleculesThe Journal of Chemical Physics, 1957
- Electrolytic Properties of Aqueous Solutions of Polyacrylic Acid and Sodium Hydroxide. II. Diffusion Experiments Using Radioactive Sodium1Journal of the American Chemical Society, 1950