Catalytic Behavior of Optically Active Amino Alcohol–Borane Complex in the Enantioselective Reduction of Acetophenone Oxime O-Alkyl Ethers
- 1 January 1987
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 60 (1), 395-396
- https://doi.org/10.1246/bcsj.60.395
Abstract
In the presence of the optically active amino alcohol–borane complex, an oxime ether was reduced with various hydride reducing agents to give a chiral primary amine of high optical purity. Catalytic use of the chiral complex was also investigated.Keywords
This publication has 3 references indexed in Scilit:
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- Selective reductions. 27. Reaction of alkyl halides with representative complex metal hydrides and metal hydrides. Comparison of various hydride reducing agentsThe Journal of Organic Chemistry, 1980