Intramolecular forces in the water molecule in lithium sulfate monohydrate
- 15 February 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 62 (4), 1473-1479
- https://doi.org/10.1063/1.430608
Abstract
A study of the low−temperature infrared spectra of varyingly deuterated mulls of lithium sulfate monohydrate has afforded information on the origin of bands due to the vibrations of the water molecule in the solid. Assignments are made for the intermolecularly uncoupled modes which produce these bands in the spectrum and intramolecular coupling force constants are calculated.Keywords
This publication has 15 references indexed in Scilit:
- The Infrared Spectrum of Ethylene Oxide Clathrate Hydrate at 100°K between 4000 and 360 cm−1Canadian Journal of Chemistry, 1973
- The Vibrational Spectra of Water of Crystallization in Barium Chlorate Monohydrate, Calcium Sulfate Dihydrate and Copper Chloride Dihydrate CrystalsBulletin of the Chemical Society of Japan, 1972
- Far Infrared Spectra and the Calculation of Lattice Vibrations of Benzoic AcidBulletin of the Chemical Society of Japan, 1972
- Intramolecular Interactions in the Water Molecule: The Stretch–Stretch Interaction Force Constant of Water Molecules in Hydrogen-Bonded SystemsThe Journal of Chemical Physics, 1970
- Structure of ice IIIActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1968
- Neutron-Diffraction Study of Lithium Sulfate MonohydrateThe Journal of Chemical Physics, 1968
- On hydrogen bonds in crystalline hydratesActa Crystallographica, 1965
- The crystal structure of Li2SO4.H2O. A three-dimensional refinementActa Crystallographica, 1965
- Method of Adjusting Force Constants and Its Application to H2O, H2CO, CH2Cl, and Their Deuterated MoleculesThe Journal of Chemical Physics, 1965
- Stretching Frequencies as a Function of Distances in Hydrogen BondsJournal of the American Chemical Society, 1955