Formation of η2 C−H Agostic Rhodium Arene Complexes and Their Relevance to Electrophilic Bond Activation
- 17 November 1998
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 120 (48), 12539-12544
- https://doi.org/10.1021/ja982534u
Abstract
No abstract availableThis publication has 31 references indexed in Scilit:
- Activation of C−H Bonds by Metal ComplexesChemical Reviews, 1997
- Replacement of a Cyclometalated Terdentate Diamino Ligand by a Phosphorus Analogue. Isolation and Crystallographic Characterization of an Intermediate in Aryl C−H Bond Activation in Models of Dendrimer-Bound Organometallic CatalystsJournal of the American Chemical Society, 1997
- Transition Metal Alkane Complexes†Chemical Reviews, 1996
- Facile reversible metalation in an agostic complex and hydrogenolysis of a metal aryl complex via a dihydrogen complexOrganometallics, 1992
- Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexesChemical Reviews, 1990
- Comparative reactivities of hydrocarbon carbon-hydrogen bonds with a transition-metal complexAccounts of Chemical Research, 1989
- Aliphatic versus aromatic carbon-hydrogen activation and the x-ray crystal structure of [IrH(H2O)(7,8-benzoquinolinato)(PPh3)2]SbF6Organometallics, 1989
- .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bondsJournal of the American Chemical Society, 1987
- Activation of arene carbon-hydrogen bonds. Highly regioselective, electrophilic aromatic metalation with rhodium(III) porphyrin and subsequent cleavage of carbon-rhodium bondOrganometallics, 1986
- Mechanism of arene carbon-hydrogen bond activation by (C5Me5)Rh(PMe3)(H)Ph. Evidence for arene precoordinationJournal of the American Chemical Society, 1982