Über Diels‐Alder‐Reaktionen des C60‐Fullerens Vorläufige Mitteilung
- 30 June 1993
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 76 (4), 1626-1631
- https://doi.org/10.1002/hlca.19930760419
Abstract
On Diels‐Alder Reactions of the C60‐FullereneWe report on the regioselective [4+2] cycloaddition of Buckminsterfullerene C60(1) at room temperature with 2,3‐dimethylbuta‐1,3‐diene and with the monoterpene 7‐methyl‐3‐methylideneocta‐1,6‐diene (= myrcene) and on the spectroscopic characterization of the corresponding crystalling monoadducts 2 and 3. According to these experiments, 1 acts as a reactive dienophile, which can be functionalized regioselectively under mild and controlled conditons.This publication has 25 references indexed in Scilit:
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