THE VISCOSITY OF CARBON DIOXIDE IN THE CRITICAL REGION

Abstract
Measurements of the viscosity of carbon dioxide in the critical region have been made with great precision by means of an oscillating disc viscosimeter. The variation of viscosity with temperature at constant density has been determined for 14 different densities. Isothermals have been evaluated from a plot of the isochores. One isothermal was determined directly and is in agreement with those determined indirectly.The form of the viscosity-temperature isochores is not the same as that found by Mason and Maass (12) for ethylene, in that there is no minimum at the critical temperature nor even up to 7 °C. above. For the region just above the condensation temperature, the viscosity is more dependent on density than on temperature; the isochores are almost flat and are well separated. However, the isothermals are spread between an upper and a lower limit of density, showing that viscosity is not entirely independent of temperature. Time lags were observed in the present investigation in the opposite direction to those observed by Geddes and Maass (9); this would appear to decrease the strength of their claims that the time lags that they observed are due to the formation of a structure in the liquid state.