Glycosylation Using a Thioglycoside and Methyl Trifluoro-Methanesulfonate. A New and Efficient Method for CIS and Trans Glycoside Formation
- 1 May 1987
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 6 (2), 301-306
- https://doi.org/10.1080/07328308708058879
Abstract
For the synthesis of large oligosaccharides and biologically active oligosaccharide derivatives it is often desirable to use a block synthesis, that is to link an oligosaccharide residue to another or to a non-carbohydrate aglycon. It is sometimes difficult to prepare glycosyl halide derivatives of the oligosaccharides in good yields, and there is a need for glycosylating agents which can be prepared under mild conditions and in good yields.Keywords
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