Space charge relaxation in polyetherimides by the electric modulus formalism

Abstract

Dynamic electrical analysis shows that at high temperatures (above the glass transition temperature), the electrical properties of polyetherimide are strongly influenced by space charge. In this article we have studied the relaxation of space charge in two commercial varieties of polyetherimide: Ultem 1000 and Ultem 5000. Their conductive properties were determined by dynamic electrical analysis, using the electric modulus formalism. The complex part of the electric modulus was fitted to Coelho’s model which considers ohmic conductivity and diffusion as the prevailing charge transport mechanisms. The complex part of the electric modulus exhibits a peak in the low frequency range that can be associated with space charge. A good agreement between experimental and calculated data is observed after the fitting process to Coelho’s model. Differences in the electrode behavior were required: blocking electrode conditions in the case of Ultem 5000 and partially blocking electrode for Ultem 1000. In both cases the conductivity determined is thermally activated and it increases with the temperature due to an increasing mobility, as their carrier densities do not vary significantly in the temperature range studied.