Photochemical Activation of the N≡N Bond in a Dimolybdenum–Dinitrogen Complex: Formation of a Molybdenum Nitride
- 10 October 2001
- journal article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 40 (20), 3907-3909
- https://doi.org/10.1002/1521-3773(20011015)40:20<3907::aid-anie3907>3.0.co;2-#
Abstract
Photoinduced cleavage of the residual N-N bond in the dimetallahydrazone 1 (Mes=2,4,6-Me3 C6 H2 ) led to a transient monomeric nitrido complex, which reacts further with 1 to form 2. Compound 1 was synthesized by the reductive arylation of MoCl4 ⋅DME by MesMgBr under an N2 atmosphere.This publication has 22 references indexed in Scilit:
- Dinitrogen Rearranging over a Metal−Oxo Surface and Cleaving to Nitride: From the End-On to the Side-On Bonding Mode, to the Stepwise Cleavage of the N⋮N Bonds Assisted by NbIII-calix[4]areneJournal of the American Chemical Society, 2000
- Dinitrogen Cleavage Stemming from a Heterodinuclear Niobium/Molybdenum N2 Complex: New Nitridoniobium Systems Including a Niobazene Cyclic TrimerOrganometallics, 2000
- In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment: Unusual Structure of a Dimolybdenum μ-Nitrido ComplexInorganic Chemistry, 1999
- Reductive Cleavage of Dinitrogen by a Vanadium Diamidoamine Complex: the Molecular Structures of [V(Me3SiN{CH2CH2NSiMe3}2)(μ-N)]2 and K[V(Me3SiN{CH2CH2NSiMe3}2)(μ-N)]2Journal of the American Chemical Society, 1999
- Stepwise Reduction of Dinitrogen Occurring on a Divanadium Model Compound: A Synthetic, Structural, Magnetic, Electrochemical, and Theoretical Investigation on the [VNNV]n+[n= 4−6] Based ComplexesJournal of the American Chemical Society, 1997
- Atom‐Bridged Intermediates in N‐ and P‐Atom Transfer ReactionsAngewandte Chemie International Edition in English, 1997
- Identifizierung verbrückter Intermediate bei N‐ und P‐TransferreaktionenAngewandte Chemie, 1997
- Dinitrogen Cleavage by Three-Coordinate Molybdenum(III) Complexes: Mechanistic and Structural Data1Journal of the American Chemical Society, 1996
- Nitrogen Atom Transfer Coupled with Dinitrogen Cleavage and Mo−Mo Triple Bond FormationJournal of the American Chemical Society, 1996
- Recent advances in the chemistry of nitrogen fixationChemical Reviews, 1978