Einwirkung von Bortrichlorid auf Aryl‐allyl‐äther; meta‐Umlagerung von Mesityl‐allyl‐äther
- 1 January 1960
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 43 (1), 448-452
- https://doi.org/10.1002/hlca.19600430157
Abstract
Unter geeigneten Bedingungen lagert Bortrichlorid in hoher Ausbeute p‐Tolyl‐allyl‐äther in 2‐Allyl‐4‐methyl‐phenol, 2,6‐Dimethylphenyl‐allyl‐äther in ein Gemisch aus 2,6‐Dimethyl‐3‐allyl‐phenol und 2,6‐Dimethyl‐4‐allyl‐phenol, und Mesityl‐allyl‐äther in 3‐Allylmesitol um. Die Umlagerungsreaktion verläuft intramolekular über die entsprechend substituierten Cyclohexa‐3,5‐dien‐1‐one.This publication has 4 references indexed in Scilit:
- Factors Controlling Position of Alkylation of Alkali Metal Salts of Phenols, Benzyl and Allyl Halides1,2Journal of the American Chemical Society, 1958
- The para Claisen Rearrangement: Rearrangement of 6-Allyl-2,6-dimethyl-2,4-cyclohexadienone1Journal of the American Chemical Society, 1957
- The Mode of Addition of a Grignard Reagent to an Aryl Allyl Ether1Journal of the American Chemical Society, 1953
- The Action of Aluminum Bromide on Allyl Phenyl EtherJournal of the American Chemical Society, 1952