TWO NEW PAPILIONACEOUS ALKALOIDS: ARGYROLOBINE AND (−)-APHYLLIDINE
- 1 April 1964
- journal article
- research article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 42 (4), 764-769
- https://doi.org/10.1139/v64-115
Abstract
Argyrolobiummegarhizum Bol. has been found to contain a number of alkaloids, four of which have been well characterized. Two of these were identical with N-methylcytisine and cytisine respectively, while the other two were new. One of these proved to be the levorotatory enantiomorph of aphyllidine, while the other (the major alkaloid), C15H22O2N2, designated argyrolobine, was shown to be a hydroxyaphyllidine, and its absolute configuration derived by reduction to (−)-sparteine.This publication has 2 references indexed in Scilit:
- Unsaturated Amines. IV. Structures and Reactions of the Dehydrosparteines and their Salts1—3Journal of the American Chemical Society, 1955
- The Papilionaceous Alkaloids. II. Baptisia australis (L.) R. Br.1Journal of the American Chemical Society, 1948