Infrared spectrum of the water dimer in solid nitrogen. II. Temperature and irradiation effects
- 1 May 1977
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 66 (9), 4073-4077
- https://doi.org/10.1063/1.434479
Abstract
The water dimer in solid nitrogen may exist in a stable and a metastable form. Transitions between the two forms are initiated by infrared radiation absorbed by the dimer fundamentals. The metastable form reverts to the stable form by a dark process. D‐donating DOH may be transformed into H‐donating HOD by infrared radiation. H‐donating HOD is metastable and changes back to D‐donating DOH by a dark (thermal) process.Keywords
This publication has 6 references indexed in Scilit:
- Infrared spectrum of the water dimer in solid nitrogen. I. Assignment and force constant calculationsThe Journal of Chemical Physics, 1977
- On the structure of the water dimerChemical Physics Letters, 1975
- Spectre infrarouge et structure de l’eau dans les matrices de gaz inertesJournal de Chimie Physique et de Physico-Chimie Biologique, 1975
- Vibrational relaxation of matrix-isolated ammonia studied by infrared double resonanceChemical Physics Letters, 1973
- Matrix-Isolation Study of the Water Dimer in Solid NitrogenThe Journal of Chemical Physics, 1970
- Infrared Studies of Hydrogen Bonding of Water by the Matrix Isolation TechniqueThe Journal of Chemical Physics, 1957