Abstract
Relative production cross sections for beam (Z1) and target (Z2) K vacancies in heavyion collisions are explained for situations where Z1Z2. Electron promotion creates a vacancy in the 2pσ molecular orbital. As the collision partners retreat, the vacancy has a probability w(v1, Z1, Z2)<~12 to be transferred to the 1s level of the higher-Z collision partner. With a charge-transfer theory of Demkov, a universal form for w is obtained, which is in excellent agreement with all available data for Ni, Br, and I beams over extended target and energy ranges.