Thermal Relaxation near the Critical Point
- 1 November 1972
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 6 (5), 1915-1920
- https://doi.org/10.1103/physreva.6.1915
Abstract
We have measured thermal-relaxation times () near the critical point of . remains small in one-phase states throughout the critical region. In two-phase states, increases as the critical temperature () is approached in proportion to at all densities. An extra increase in occurs in two-phase states very near the phase boundary. These observations suggest to us that the diffusion of matter across the liquid-vapor interface is a bottle-neck for equilibration. Our data are of value in interpreting puzzling features of several other experiments near critical points.
Keywords
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