Aerobic Oxidation of Cyclohexane Catalyzed by Fe(III)(5,10,15,20-tetrakis(pentafluorophenyl)porphyrin)Cl in Sub- and Super-Critical CO2
- 1 October 1997
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 26 (10), 1045-1046
- https://doi.org/10.1246/cl.1997.1045
Abstract
Aerobic oxidation of cyclohexane to yield cyclohexanol and cyclohexanone in the presence of a Fe-porphyrin catalyst bearing meso-pentafluorophenyl group and acetaldehyde has been efficiently enhanced in pressurized CO2. The reaction rate takes a maximum value in the neighborhood of critical pressure.Keywords
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