Absorption of Sound Near the Critical Point of the Nitrobenzene—Iso-octane System
- 1 April 1966
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (7), 2651-2658
- https://doi.org/10.1063/1.1727106
Abstract
Measurements by the pulse technique were made of the absorption of sound in the nitrobenzene—iso‐octane system (Tc=30.2°C) over the full composition range, at temperatures of 30.5°C, 34.8°, and 44.8° for five frequencies between 4.5 and 16.5 Mc/sec. At the lowest frequency and at 0.3°C above the critical temperature, the absorption is anomalously large by a factor of 47; 14.6°C above Tc, the absorption is still in excess of classical predictions by a factor of 11. The data cannot be represented by a model involving only a single relaxation frequency. The Fixman theory is in reasonable, but not exact, agreement with the data with regard to functional conformity in temperature and frequency; in particular, the predicted frequency dependence, α/f2∝f−5/4, at the critical state is verified within experimental error. The Fixman theory and the data preclude anything but a simple pole at the critical temperature for the reciprocal square of κ, the exponential decay constant in the long‐range correlation function. However, if it is assumed that the theory and experiment are in agreement over the full range of temperature and frequency, with a value of a1=0.0296.
Keywords
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