Michael Addition of Selenoamides to α,β-Unsaturated Carbonyl Compounds: Stereocontrolled Synthesis of δ-Oxo Selenoamides and Their Reactivity
- 6 January 2000
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (3), 311-313
- https://doi.org/10.1021/ol990365s
Abstract
[reaction: see text] Lithium eneselenolates generated from selenoamides underwent Michael addition to alpha,beta-unsaturated esters and ketones with high diastereoselectivity to give delta-oxo selenoamides in moderate to high yields within a few seconds. Further selective transformations of the delta-oxo selenoamides were also achieved.Keywords
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