Abstract
In previous publications a first‐principles method was developed for constructing second‐quantization representations for systems of composite bound states and their constituents. It is based on the introduction of redundant modes (’’ideal atom variables’’) which are given physical content by carrying out a suitable unitary transformation. A single transformed Hamiltonian explicitly and simultaneously exhibits all kinematically possible scattering and reaction channels. Most of the previous results were limited to the case of two fermion composites. This restriction is removed herein, in order to allow a first‐principles approach to the many‐particle quantum dynamics and statistics of chemical and nuclear reactions. The kinematical aspects of the relevant transformation are examined.