Xenon Tetrafluoride: Fluorine-19 High-Resolution Magnetic Resonance Spectrum
- 12 April 1963
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 140 (3563), 178
- https://doi.org/10.1126/science.140.3563.178
Abstract
The F19 spectrum of XeF4 dissolved in anhydrous hydrogen fluoride has been observed at two frequencies, yielding a F19 chemical shift of 175 parts per million to lower field than the solvent and a Xe129-F19 spin-spin coupling constant, confirmed by double irradiation, of 3860 cycles per second. Absence of fast F19 chemical exchange and collapse of the Xe131-F19 coupling by quadrupole relaxation may be inferred from the spectrum.Keywords
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